laitimes

Historically, dangerous chemical accidents occurred in March

author:Qingbaijiang emergency

Petrochemical

Hubei Jingzhou Petrochemical General Plant "3•30" ethylene oxide explosion accident

On March 30, 1999, an explosion accident occurred in the production process of Jingzhou Petrochemical General Plant in Hubei Province, resulting in the death of 4 people and direct economic losses of 450,000 yuan. The direct cause of the accident is that the petrochemical plant does not know the characteristics of raw materials, there is no flow meter on the site, and the feed speed cannot be controlled, causing the feed speed of ethylene oxide to be too fast, and it is too late to react with propynyl alcohol and accumulate in the kettle, resulting in a rapid rise in the pressure in the kettle, breaking through the blasting membrane, and the high-pressure gas is sharply spewed out to produce static electricity to cause an explosion.

Hebei Baoding petrochemical plant "3•31" slag tank welding operation explosion accident

On March 31, 1984, an explosion occurred in the residual oil tank of the petrochemical plant in Baoding City, Hebei Province, which affected two gasoline tanks with a volume of 1800 m3 at a distance of 20 meters, causing the gasoline tank to explode and catch fire, killing 16 people and seriously injuring 6 people. The direct cause of the accident was: the plant illegally transported residual oil, the oil temperature was too high, a combustible gas was formed in the tank farm, and the employees carried out welding operations in violation of regulations, detonating the flammable gas, resulting in the accident.

Fine chemicals

Jiangsu Xiangshui Tianjiayi Chemical Co., Ltd. "3•21" special major explosion accident

At about 14:48 on March 21, 2019, a particularly serious explosion accident occurred at Tianjiayi Chemical Co., Ltd., located in the Xiangshui County Ecological Chemical Park in Yancheng City, Jiangsu Province, causing 78 deaths, 76 serious injuries, 640 hospitalizations, and direct economic losses of 1.986 billion yuan. The direct cause of the accident was that the nitrification waste stored illegally in the old solid waste warehouse of Tianjiayi Company continued to heat up and led to spontaneous combustion, which in turn caused the nitrification waste to explode.

Anhui Anqing Xinfu Chemical Co., Ltd. "3 • 27" explosion accident

On March 27, 2011, the no. 3 low-temperature chlorination kettle in the manufacturing workshop of Anhui Anqing Xinfu Chemical Co., Ltd. exploded, causing a local fire in the workshop, causing 3 deaths and 1 minor injury to the personnel on duty. The direct cause of the accident is: the operator on duty misoperated, and when preparing to add dimethylformamide, the methanol high tank valve was mistakenly opened, and the remaining methanol of the high tank used for washing the kettle was added to the kettle, and a violent reaction occurred with the material in the kettle, resulting in an explosion.

chemical fertilizer

Inner Mongolia Tianrun Fertilizer Company "3•3" large burning accident

On March 3, 2015, during the inspection and maintenance process, Inner Mongolia Tianrun Fertilizer Co., Ltd. dismantled the flange blind plate at the bottom of the gas-liquid separator of the gas-liquid separator of the gasifier, and the high-pressure steam spewed out, causing 3 operators (2 inspection and maintenance personnel and 1 guardian) to burn and die. The direct cause of the accident was that the relevant departments of the company issued a maintenance work ticket when the production system had not stopped; the maintenance personnel disassembled the flange blind plate without confirmation, causing high-pressure steam to spew out, resulting in the accident.

Organic chemicals

Hebei Tangshan Huayi Industrial Company "3•1" large explosion accident

At about 12:20 on March 1, 2018, Huayi Industrial Co., Ltd. of Tangshan City, Hebei Province, organized contractor Qian'an Tianliang Construction Mechanical and Electrical Installation Engineering Co., Ltd. to carry out sewage tank inspection and maintenance operations in the benzene hydrogenation workshop, and a combustion and explosion accident occurred, resulting in 4 deaths and 1 injury. The direct cause of the accident was: a small amount of benzene organic matter was contained in the dissolved salt sewage of the benzene hydrogenation workshop, which accumulated in the sewage tank and volatilized into the vapor phase space above the liquid surface; the management of Huayi Company's fire operation was not in place, and the ignition source generated by the operators during the inspection and maintenance operation on the top of the tank caused the combustible gas on the top of the tank to catch fire, which then caused the ignition explosion.

Inorganic chemicals

Sichuan Tianyi Chemical Co., Ltd. "3•1" explosion accident

On March 1, 2014, an explosion occurred at the production site of the No. 2 yellow phosphorus smelting furnace of Sichuan Tianyi Chemical Co., Ltd., causing 3 deaths and direct economic losses of about 6 million yuan. The direct cause of the accident was: the company's No. 2 furnace bottom refractory brick failure, the sinking of the molten pool, the burning of the bottom of the furnace, the leakage of molten phosphorus iron and phosphorus slag in the wet explosion, some maintenance personnel avoided danger, resulting in casualties and accidents.

Hebei Weixian Hongshun Chemical Raw Materials Co., Ltd. "3• 29" poisoning suffocation accident

On March 29, 2013, Hebei Weixian Hongshun Chemical Raw Materials Co., Ltd. was poisoned and suffocated in the process of eliminating the blockage of carbon disulfide condensing pipeline, resulting in 3 deaths, 2 minor injuries, and direct economic losses of about 2 million yuan. The direct cause of the accident is: after the fire operator found that the pipeline was blocked, he did not report to the factory in time, and without taking any preventive measures, he opened the toxic gas pipeline in operation without authorization to dredge the dredging mouth of the soil to block, and dredged the blocked pipeline, causing a large amount of hydrogen sulfide and carbon disulfide gas to leak, and the operator was poisoned and fainted after inhaling the toxic gas and fell into the pool. The 4 operators did not take any protective measures, blindly rescued, and were poisoned and fainted, resulting in the expansion of the accident.

Luliang County, Yunnan Province Hongying Phosphorus Industry Co., Ltd. "3 • 13" poisoning suffocation accident

On March 13, 2011, Hongying Phosphorus Industry Co., Ltd. of Luliang County, Yunnan Province, was poisoned in the process of cleaning up the mud and phosphorus in the 1# refining tank of the 2# yellow phosphorus furnace, resulting in 3 deaths of contractor workers and 1 injury and hospitalization. The direct cause of the accident is: when the operator is carrying out dredging operations, with the continuous clearance of mud and phosphorus, the water level in the 1# refining tank continues to decline, and some of the mud and phosphorus are exposed to the water surface, spontaneously combusting after encountering air, producing a large number of toxic and harmful gases, resulting in the inhalation of toxic and harmful gases by the personnel in the tank.

Jiangsu Wuxi Chemical Group Volkswagen Chemical Plant "3•24" explosion accident

On March 24, 1995, an explosion occurred in the mixed barrel of the mixed packaging post in the rear road of the insurance powder workshop of the volkswagen chemical factory of Jiangsu Wuxi Chemical Group Co., Ltd., killing 6 people and injuring 5 people. The direct cause of the accident is: the material in the mixing barrel is unqualified and the heat is released, the temperature of the material is increased, the decomposition is intensified, and the mixing barrel is seriously overdose, blocking the exhaust port, so that the sulfur dioxide gas released by the part rises sharply in the barrel, resulting in the explosion of the mixing barrel.

medicine

Gasoline deflagration accident in the "3•9" ice chip workshop of Fuding County Pharmaceutical Factory in Fujian Province

On March 9, 1982, a gasoline deflagration accident occurred in the ice chip workshop of Fujian Fuding County Pharmaceutical Factory, causing 65 deaths, 35 injuries, and direct economic losses of more than 390,000 yuan. The direct cause of the accident was that the operator was pumping oil from the crystallization tank with a PVC pipe (during the ice chip making process, gasoline was used as the ice flake crystallization dissolving liquid), and the PVC pipe without a grounding device generated static electricity during the pumping process and caused a fire. After the fire broke out, the command was wrong, the fire extinguishing method was improper, and the continuous deflagration and sealing of the retreat path led to the expansion of the accident.

Rubber and plastic manufacturing

Sichuan Jinlu Resin Co., Ltd. "3• 16" vinyl chloride poisoning accident

On March 16, 2016, a vinyl chloride poisoning accident occurred during the overhaul operation of The polymerization experimental device 1# of Sichuan Jinlu Resin Co., Ltd., resulting in 3 deaths and 2 injuries. The direct cause of the accident is: employees violate the operating procedures into the restricted space operation, in the case of the reactor and the system are not safely isolated according to the regulations, vinyl chloride is strung into the reactor in operation to cause poisoning of personnel, coupled with the rescue personnel in the case of not wearing an isolated respirator, tied to the safety rope into the kettle blindly rescue, resulting in the expansion of the consequences of the accident.

other

Sichuan Province Wong Fu Da Zhou Chemical Co., Ltd. "3.3" hydrogen sulfide poisoning accident

On March 3, 2019, a hydrogen sulfide gas poisoning accident occurred in the phosphoric acid filling area of the logistics department of Sichuan OngfuDazhou Chemical Co., Ltd., resulting in 3 deaths and 3 injuries. The direct cause of the accident was: the transport vehicle of the Navigation Company (the transport service provider of Ongfudazhou Chemical Co., Ltd.) still had residual liquid after transporting liquid sodium sulfide unloading, and when the transporter escort used low-pressure steam to purge and clean the tank of the transport vehicle, the residual sodium sulfide in the vehicle flowed into the gutter with the steam tank sewage, and chemically reacted with the residual phosphoric acid in the gutter, producing hydrogen sulfide gas, causing nearby personnel to inhale poisoning.

Liaoning Jianping County Hongshen Trading Co., Ltd. "3•1" sulfuric acid storage tank explosion accident

On March 1, 2013, an explosion of sulfuric acid storage tanks occurred in Liaoning Jianping County Hongshen Trading Co., Ltd., resulting in 7 deaths, 2 injuries, and direct economic losses of 12.1 million yuan. The direct cause of the accident is: after the concentrated sulfuric acid in the sulfuric acid storage tank is partially diluted, it reacts with the material of the storage tank to produce hydrogen, and forms an explosive mixture of gas with the air containing oxygen, when the mixed gas comes out of the vent pipe vent and the small gap around the tank roof, it is caused by welding open fire, resulting in the bursting of the No. 2 tank. The fragments of the tank that flew out smashed the lower connection pipe flange of the No. 1 storage tank, and the sulfuric acid in the tank leaked. The sulfuric acid leaked from tanks 2 and 1 flows into nearby farmland, riverbeds and highway culverts, causing serious secondary environmental disasters.

Source | Ministry of Emergency Management